DL 162 then HV 6335 at Schiphol
Minneapolis → Amsterdam → Valencia
Timetable, Amsterdam time
10:35DL 162 from Minneapolis at the gate
07:10HV 6335 to Valencia leaves the gate
20 h 35 apart on the timetable, overnight
HV 6335 leaves 20 h 35 after DL 162 arrives on the timetable: more than half a day, so not a connection we count.