KL 1008 then KL 2659 at Schiphol
London Heathrow → Amsterdam → Valencia
Timetable, Amsterdam time
16:20KL 1008 from London Heathrow at the gate
06:50KL 2659 to Valencia leaves the gatealso HV 6331
14 h 30 apart on the timetable, overnight
KL 2659 leaves 14 h 30 after KL 1008 arrives on the timetable: more than half a day, so not a connection we count.