KL 1500 then KL 2659 at Schiphol
Madrid → Amsterdam → Valencia
Timetable, Amsterdam time
08:35KL 1500 from Madrid at the gatealso KQ 1698
06:50KL 2659 to Valencia leaves the gatealso HV 6331
22 h 15 apart on the timetable, overnight
KL 2659 leaves 22 h 15 after KL 1500 arrives on the timetable: more than half a day, so not a connection we count.