KL 1502 then HV 6335 at Schiphol
Madrid → Amsterdam → Valencia
Timetable, Amsterdam time
13:25KL 1502 from Madrid at the gate
07:10HV 6335 to Valencia leaves the gate
17 h 45 apart on the timetable, overnight
HV 6335 leaves 17 h 45 after KL 1502 arrives on the timetable: more than half a day, so not a connection we count.