KL 1530 then U2 2170 at Schiphol
Valencia → Amsterdam → Manchester
Timetable, Amsterdam time
08:40KL 1530 from Valencia at the gate
21:40U2 2170 to Manchester leaves the gate
13 h apart on the timetable
U2 2170 leaves 13 h after KL 1530 arrives on the timetable: more than half a day, so not a connection we count.