KL 1530 then U2 3302 at Schiphol
Valencia → Amsterdam → Edinburgh
Timetable, Amsterdam time
08:40KL 1530 from Valencia at the gate
22:15U2 3302 to Edinburgh leaves the gate
13 h 35 apart on the timetable
U2 3302 leaves 13 h 35 after KL 1530 arrives on the timetable: more than half a day, so not a connection we count.