KL 1850 then HV 6335 at Schiphol
Munich → Amsterdam → Valencia
Timetable, Amsterdam time
11:35KL 1850 from Munich at the gate
07:20HV 6335 to Valencia leaves the gate
19 h 45 apart on the timetable, overnight
HV 6335 leaves 19 h 45 after KL 1850 arrives on the timetable: more than half a day, so not a connection we count.