KL 652 then VY 1061 at Schiphol
Washington → Amsterdam → Barcelona
Timetable, Amsterdam time
07:05KL 652 from Washington at the gate
19:15VY 1061 to Barcelona leaves the gate
12 h 10 apart on the timetable
VY 1061 leaves 12 h 10 after KL 652 arrives on the timetable: more than half a day, so not a connection we count.