KL 678 then HV 6335 at Schiphol
Calgary → Amsterdam → Valencia
Timetable, Amsterdam time
08:25KL 678 from Calgary at the gate
07:10HV 6335 to Valencia leaves the gate
22 h 45 apart on the timetable, overnight
HV 6335 leaves 22 h 45 after KL 678 arrives on the timetable: more than half a day, so not a connection we count.