KL 690 then HV 6335 at Schiphol
Cancún → Amsterdam → Valencia
Timetable, Amsterdam time
08:30KL 690 from Cancún at the gate
07:10HV 6335 to Valencia leaves the gate
22 h 40 apart on the timetable, overnight
HV 6335 leaves 22 h 40 after KL 690 arrives on the timetable: more than half a day, so not a connection we count.