KL 9864 then AC 809 at Schiphol
Brussels → Amsterdam → Toronto
Timetable, Amsterdam time
13:32KL 9864 from Brussels at the gate
12:05AC 809 to Toronto leaves the gate
22 h 33 apart on the timetable, overnight
AC 809 leaves 22 h 33 after KL 9864 arrives on the timetable: more than half a day, so not a connection we count.