KL 9864 then KL 677 at Schiphol
Brussels → Amsterdam → Calgary
Timetable, Amsterdam time
13:32KL 9864 from Brussels at the gate
12:20KL 677 to Calgary leaves the gate
22 h 48 apart on the timetable, overnight
KL 677 leaves 22 h 48 after KL 9864 arrives on the timetable: more than half a day, so not a connection we count.