KL 9864 then KL 681 at Schiphol
Brussels → Amsterdam → Vancouver
Timetable, Amsterdam time
13:32KL 9864 from Brussels at the gate
12:50KL 681 to Vancouver leaves the gate
23 h 18 apart on the timetable, overnight
KL 681 leaves 23 h 18 after KL 9864 arrives on the timetable: more than half a day, so not a connection we count.