KL 9864 then KL 691 at Schiphol
Brussels → Amsterdam → Toronto
Timetable, Amsterdam time
13:32KL 9864 from Brussels at the gate
13:30KL 691 to Toronto leaves the gate
23 h 58 apart on the timetable, overnight
KL 691 leaves 23 h 58 after KL 9864 arrives on the timetable: more than half a day, so not a connection we count.