SK 6701 then HV 6331 at Schiphol
Madrid → Amsterdam → Valencia
Timetable, Amsterdam time
08:35SK 6701 from Madrid at the gate
06:40HV 6331 to Valencia leaves the gate
22 h 05 apart on the timetable, overnight
HV 6331 leaves 22 h 05 after SK 6701 arrives on the timetable: more than half a day, so not a connection we count.