U2 7900 then KL 1855 at Schiphol
Valencia → Amsterdam → Munich
Timetable, Amsterdam time
17:50U2 7900 from Valencia at the gate
15:20KL 1855 to Munich leaves the gate
21 h 30 apart on the timetable, overnight
KL 1855 leaves 21 h 30 after U2 7900 arrives on the timetable: more than half a day, so not a connection we count.