U2 7900 then KL 595 at Schiphol
Valencia → Amsterdam → Cape Town
Timetable, Amsterdam time
22:00U2 7900 from Valencia at the gate
17:15KL 595 to Cape Town leaves the gate
19 h 15 apart on the timetable, overnight
KL 595 leaves 19 h 15 after U2 7900 arrives on the timetable: more than half a day, so not a connection we count.