U2 7900 then KL 695 at Schiphol
Valencia → Amsterdam → Toronto
Timetable, Amsterdam time
17:50U2 7900 from Valencia at the gate
16:50KL 695 to Toronto leaves the gate
23 h apart on the timetable, overnight
KL 695 leaves 23 h after U2 7900 arrives on the timetable: more than half a day, so not a connection we count.