A3 629 then A3 622 at Athens
Luxembourg → Athens → Brussels
Timetable, Athens time
21:55A3 629 from Luxembourg at the gate
16:40A3 622 to Brussels leaves the gate
18 h 45 apart on the timetable, overnight
A3 622 leaves 18 h 45 after A3 629 arrives on the timetable: more than half a day, so not a connection we count.