U2 2059 then A3 166 at Athens
Manchester → Athens → Ioannina
Timetable, Athens time
20:50U2 2059 from Manchester at the gate
19:20A3 166 to Ioannina leaves the gate
22 h 30 apart on the timetable, overnight
A3 166 leaves 22 h 30 after U2 2059 arrives on the timetable: more than half a day, so not a connection we count.