AA 5063 then DL 5245 at Atlanta
Charlotte → Atlanta → Knoxville
Timetable, Atlanta time
08:42AA 5063 from Charlotte at the gate
08:11DL 5245 to Knoxville leaves the gate
23 h 29 apart on the timetable, overnight
DL 5245 leaves 23 h 29 after AA 5063 arrives on the timetable: more than half a day, so not a connection we count.