DL 5227 then DL 589 at Atlanta
Asheville → Atlanta → Mexico City
Timetable, Atlanta time
19:14DL 5227 from Asheville at the gate
19:12DL 589 to Mexico City leaves the gate
23 h 58 apart on the timetable, overnight
DL 589 leaves 23 h 58 after DL 5227 arrives on the timetable: more than half a day, so not a connection we count.