KL 623 then DL 2094 at Atlanta
Amsterdam → Atlanta → Des Moines
Timetable, Atlanta time
13:35KL 623 from Amsterdam at the gate
12:59DL 2094 to Des Moines leaves the gate
23 h 24 apart on the timetable, overnight
DL 2094 leaves 23 h 24 after KL 623 arrives on the timetable: more than half a day, so not a connection we count.