AZ 74 then FR 133 at Barcelona
Rome → Barcelona → Berlin
Timetable, Barcelona time
10:50AZ 74 from Rome at the gate
07:40FR 133 to Berlin leaves the gate
20 h 50 apart on the timetable, overnight
FR 133 leaves 20 h 50 after AZ 74 arrives on the timetable: more than half a day, so not a connection we count.