AZ 76 then FR 133 at Barcelona
Rome → Barcelona → Berlin
Timetable, Barcelona time
15:55AZ 76 from Rome at the gate
07:40FR 133 to Berlin leaves the gate
15 h 45 apart on the timetable, overnight
FR 133 leaves 15 h 45 after AZ 76 arrives on the timetable: more than half a day, so not a connection we count.