AZ 76 then FR 7543 at Barcelona
Rome → Barcelona → Manchester
Timetable, Barcelona time
15:55AZ 76 from Rome at the gate
11:35FR 7543 to Manchester leaves the gate
19 h 40 apart on the timetable, overnight
FR 7543 leaves 19 h 40 after AZ 76 arrives on the timetable: more than half a day, so not a connection we count.