EC 4211 then FR 2834 at Barcelona
Napoli → Barcelona → Brussels Charleroi
Timetable, Barcelona time
17:00EC 4211 from Napoli at the gate
16:05FR 2834 to Brussels Charleroi leaves the gate
23 h 05 apart on the timetable, overnight
FR 2834 leaves 23 h 05 after EC 4211 arrives on the timetable: more than half a day, so not a connection we count.