EC 4211 then QR 4702 at Barcelona
Napoli → Barcelona → Geneva
Timetable, Barcelona time
17:00EC 4211 from Napoli at the gate
15:15QR 4702 to Geneva leaves the gate
22 h 15 apart on the timetable, overnight
QR 4702 leaves 22 h 15 after EC 4211 arrives on the timetable: more than half a day, so not a connection we count.