EC 7110 then EW 9443 at Barcelona
Geneva → Barcelona → Düsseldorf
Timetable, Barcelona time
22:05EC 7110 from Geneva at the gate
19:35EW 9443 to Düsseldorf leaves the gate
21 h 30 apart on the timetable, overnight
EW 9443 leaves 21 h 30 after EC 7110 arrives on the timetable: more than half a day, so not a connection we count.