EC 7152 then EC 7207 at Barcelona
Milan → Barcelona → Newcastle
Timetable, Barcelona time
16:10EC 7152 from Milan at the gate
11:50EC 7207 to Newcastle leaves the gate
19 h 40 apart on the timetable, overnight
EC 7207 leaves 19 h 40 after EC 7152 arrives on the timetable: more than half a day, so not a connection we count.