EC 7152 then FR 133 at Barcelona
Milan → Barcelona → Berlin
Timetable, Barcelona time
14:25EC 7152 from Milan at the gate
07:40FR 133 to Berlin leaves the gate
17 h 15 apart on the timetable, overnight
FR 133 leaves 17 h 15 after EC 7152 arrives on the timetable: more than half a day, so not a connection we count.