EC 7152 then LA 5771 at Barcelona
Milan → Barcelona → Almeria
Timetable, Barcelona time
14:25EC 7152 from Milan at the gate
12:35LA 5771 to Almeria leaves the gate
22 h 10 apart on the timetable, overnight
LA 5771 leaves 22 h 10 after EC 7152 arrives on the timetable: more than half a day, so not a connection we count.