EC 7152 then QR 3689 at Barcelona
Milan → Barcelona → Torino
Timetable, Barcelona time
16:55EC 7152 from Milan at the gate
16:45QR 3689 to Torino leaves the gate
23 h 50 apart on the timetable, overnight
QR 3689 leaves 23 h 50 after EC 7152 arrives on the timetable: more than half a day, so not a connection we count.