EC 7152 then VY 6092 at Barcelona
Milan → Barcelona → Venezia
Timetable, Barcelona time
14:25EC 7152 from Milan at the gate
12:40VY 6092 to Venezia leaves the gate
22 h 15 apart on the timetable, overnight
VY 6092 leaves 22 h 15 after EC 7152 arrives on the timetable: more than half a day, so not a connection we count.