EC 7154 then LL 5102 at Barcelona
Milan → Barcelona → Ranon
Timetable, Barcelona time
16:10EC 7154 from Milan at the gate
14:45LL 5102 to Ranon leaves the gate
22 h 35 apart on the timetable, overnight
LL 5102 leaves 22 h 35 after EC 7154 arrives on the timetable: more than half a day, so not a connection we count.