EC 7154 then VY 1082 at Barcelona
Milan → Barcelona → Brussels
Timetable, Barcelona time
23:15EC 7154 from Milan at the gate
19:00VY 1082 to Brussels leaves the gate
19 h 45 apart on the timetable, overnight
VY 1082 leaves 19 h 45 after EC 7154 arrives on the timetable: more than half a day, so not a connection we count.