EC 7174 then FR 6332 at Barcelona
Berlin → Barcelona → Santiago de Compostela
Timetable, Barcelona time
23:05EC 7174 from Berlin at the gate
20:10FR 6332 to Santiago de Compostela leaves the gate
21 h 05 apart on the timetable, overnight
FR 6332 leaves 21 h 05 after EC 7174 arrives on the timetable: more than half a day, so not a connection we count.