EC 7194 then FR 7543 at Barcelona
Leeds → Barcelona → Manchester
Timetable, Barcelona time
12:00EC 7194 from Leeds at the gate
11:35FR 7543 to Manchester leaves the gate
23 h 35 apart on the timetable, overnight
FR 7543 leaves 23 h 35 after EC 7194 arrives on the timetable: more than half a day, so not a connection we count.