EC 7200 then FR 867 at Barcelona
Edinburgh → Barcelona → Venezia
Timetable, Barcelona time
13:30EC 7200 from Edinburgh at the gate
06:20FR 867 to Venezia leaves the gate
16 h 50 apart on the timetable, overnight
FR 867 leaves 16 h 50 after EC 7200 arrives on the timetable: more than half a day, so not a connection we count.