EC 7208 then EC 7159 at Barcelona
Newcastle → Barcelona → Milan Linate
Timetable, Barcelona time
22:55EC 7208 from Newcastle at the gate
19:05EC 7159 to Milan Linate leaves the gate
20 h 10 apart on the timetable, overnight
EC 7159 leaves 20 h 10 after EC 7208 arrives on the timetable: more than half a day, so not a connection we count.