EC 8065 then IB 5008 at Barcelona
London Gatwick → Barcelona → Amsterdam
Timetable, Barcelona time
18:40EC 8065 from London Gatwick at the gate
15:55IB 5008 to Amsterdam leaves the gatealso LL 5008
21 h 15 apart on the timetable, overnight
IB 5008 leaves 21 h 15 after EC 8065 arrives on the timetable: more than half a day, so not a connection we count.