EC 8065 then KL 1514 at Barcelona
London Gatwick → Barcelona → Amsterdam
Timetable, Barcelona time
18:40EC 8065 from London Gatwick at the gate
13:10KL 1514 to Amsterdam leaves the gate
18 h 30 apart on the timetable, overnight
KL 1514 leaves 18 h 30 after EC 8065 arrives on the timetable: more than half a day, so not a connection we count.