EC 8065 then LA 5758 at Barcelona
London Gatwick → Barcelona → Rome
Timetable, Barcelona time
18:40EC 8065 from London Gatwick at the gate
17:20LA 5758 to Rome leaves the gate
22 h 40 apart on the timetable, overnight
LA 5758 leaves 22 h 40 after EC 8065 arrives on the timetable: more than half a day, so not a connection we count.