EW 2520 then FR 5270 at Barcelona
Stuttgart → Barcelona → Manchester
Timetable, Barcelona time
14:25EW 2520 from Stuttgart at the gate
10:20FR 5270 to Manchester leaves the gate
19 h 55 apart on the timetable, overnight
FR 5270 leaves 19 h 55 after EW 2520 arrives on the timetable: more than half a day, so not a connection we count.