EW 2520 then RK 5270 at Barcelona
Stuttgart → Barcelona → Manchester
Timetable, Barcelona time
14:25EW 2520 from Stuttgart at the gate
13:45RK 5270 to Manchester leaves the gate
23 h 20 apart on the timetable, overnight
RK 5270 leaves 23 h 20 after EW 2520 arrives on the timetable: more than half a day, so not a connection we count.