EW 522 then FR 483 at Barcelona
Cologne → Barcelona → Málaga
Timetable, Barcelona time
19:45EW 522 from Cologne at the gate
16:05FR 483 to Málaga leaves the gate
20 h 20 apart on the timetable, overnight
FR 483 leaves 20 h 20 after EW 522 arrives on the timetable: more than half a day, so not a connection we count.