EW 522 then FR 5718 at Barcelona
Cologne → Barcelona → Bratislava
Timetable, Barcelona time
19:45EW 522 from Cologne at the gate
09:10FR 5718 to Bratislava leaves the gate
13 h 25 apart on the timetable, overnight
FR 5718 leaves 13 h 25 after EW 522 arrives on the timetable: more than half a day, so not a connection we count.