EW 522 then QR 3619 at Barcelona
Cologne → Barcelona → Bari
Timetable, Barcelona time
19:45EW 522 from Cologne at the gate
18:15QR 3619 to Bari leaves the gate
22 h 30 apart on the timetable, overnight
QR 3619 leaves 22 h 30 after EW 522 arrives on the timetable: more than half a day, so not a connection we count.