EW 9444 then LA 5751 at Barcelona
Düsseldorf → Barcelona → Brussels
Timetable, Barcelona time
15:35EW 9444 from Düsseldorf at the gate
14:35LA 5751 to Brussels leaves the gate
23 h apart on the timetable, overnight
LA 5751 leaves 23 h after EW 9444 arrives on the timetable: more than half a day, so not a connection we count.