FR 13 then QR 3671 at Barcelona
Vienna → Barcelona → Valladolid
Timetable, Barcelona time
19:35FR 13 from Vienna at the gate
12:20QR 3671 to Valladolid leaves the gate
16 h 45 apart on the timetable, overnight
QR 3671 leaves 16 h 45 after FR 13 arrives on the timetable: more than half a day, so not a connection we count.